Looks like you want to print to a laser printer instead of a label printer.
The label paper should be something like this:
https://www.avery.com/products/labels/5160

Here’s instruction:

Creating and Printing Labels for a Laser Printer

Avery-3X10-laser-printer-full-size-lable

You can also Hold CTRL key and hit “Print Labels” button to preview labels on the screen.